N-(3-Methoxybenzoyl)-4-methylbenzenesulfonamide
نویسندگان
چکیده
In the title compound, C15H15NO4S, the dihedral angle between the benzene rings is 88.87 (1)°. In the crystal, adjacent mol-ecules form inversion dimers through pairs of strong N-H⋯O hydrogen bonds, generating R 2 (2)(8) loops. Two C-H⋯π inter-actions and an aromatic π-π inter-action [centroid-centroid separation = 3.8191 (1) Å] are also observed.
منابع مشابه
N-(4-Methoxybenzoyl)-2-methylbenzenesulfonamide
In the title compound, C15H15NO4S, the dihedral angle between the aromatic rings is 80.81 (1)° and the dihedral angle between the planes defined by the S-N-C=O fragment and the sulfonyl benzene ring is 86.34 (1)°. In the extended structure, dimers related by a crystallographic twofold axis are connected by pairs of both N-H⋯O hydrogen bonds and C-H⋯O inter-actions, which generate R 2 (2)(8) and...
متن کاملN-(3-Methoxybenzoyl)-2-methylbenzenesulfonamide
In the title compound, C15H15NO4S, the dihedral angle between the methyl- and meth-oxy-substituted benzene rings is 88.99 (12)°. An intra-molecular C-H⋯O hydrogen bond occurs. In the crystal, adjacent mol-ecules form inversion-related dimers through strong N-H⋯O hydrogen bonds, generating R 2 (2)(8) loops. The dimers are further connected through C-H⋯O inter-actions that form C(8) chains parall...
متن کاملN-(4-Methoxyphenyl)-4-methylbenzenesulfonamide
In the title compound, C(14)H(15)NO(3)S, the dihedral angle between the aromatic rings is 59.39 (14)° and the C-S-N-C torsion angle is -71.4 (2)°. In the crystal, a supra-molecular chain running along the b axis with a C(4) graph set is formed via N-H⋯O hydrogen bonds.
متن کاملN-(4-Chloropyridin-2-yl)-N-methoxymethyl-4-methylbenzenesulfonamide
In the crystal structure of the title compound, C(14)H(15)ClN(2)O(3)S, each mol-ecule is connected via inter-molecular C-H⋯O hydrogen bonds to three further mol-ecules, generating a three-dimensional network. The 4-methyl-phenyl-sulfonyl ring forms a dihedral angle of 40.7 (2)° with the 4-chloro-pyridine ring.
متن کاملN-(2-Chlorobenzoyl)-4-methylbenzenesulfonamide
In the title compound, C(14)H(12)ClNO(3)S, the C=O bond is syn to the Cl substituent in the adjacent benzene ring. The C-S-N-C torsion angle is -80.6 (6)°. The chloro-benzoyl ring is disordered and was refined using a split model [occupancy ratio 0.537 (3):0.463 (3)]. In the crystal, mol-ecules are linked by pairs of N-H⋯O(S) hydrogen bonds, forming inversion dimers.
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عنوان ژورنال:
دوره 69 شماره
صفحات -
تاریخ انتشار 2013